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镍的双二苯膦乙烷配合物[Ni(dppe)_2](ClO_4)_2的合成与晶体结构 被引量:1

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摘要 [Ni(dppe)2](ClO4)2配合物已被合成并制的单晶(dppe为(C6H5)2-P-CH2-CH2-P-(C6H5)2).经X-射线衍射表征,晶体数据:单斜晶系,空间群P1/2(#14),a=10.845(1),b=16.198(3),c=13.890(2),β=95.2600,°V=2429.7(7)3,Z=2,Dcale=1.44(g.cm-3).[Ni(dppe)2]2+是中心对称的,并且每个Ni原子是由来自两个双膦配体的四个磷原子形成共平面的NiP4而键合的.
出处 《西北民族大学学报(自然科学版)》 2010年第2期4-6,共3页 Journal of Northwest Minzu University(Natural Science)
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