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电子束沉积生长高迁移率IMO透明导电薄膜的研究 被引量:8

High-mobility transparent conducting IMO thin films grown by reactive electron beam vapor deposition
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摘要 研究了利用电子束反应蒸发技术梯度速率生长高迁移率In2O3:Mo(IMO)薄膜的微观结构、光学和电学性能。高纯度In2O3:MoO3陶瓷靶和O2作为源材料。首先,利用低沉积速率(约0.01nm/s)生长一层厚度约为30nm的IMO薄膜,作为缓冲层,其次,提高生长速率至0.04nm/s,高速率生长IMO薄膜,薄膜厚度约50nm。典型薄膜电阻率ρ约为2.5×10-4Ωcm,方块电阻Rs约为22.5Ω,载流子浓度n~5.8×1020cm-3,电子迁移率μ约为47.1cm2V-1s-1,可见光和近红外区域平均透过率约为80%。获得的IMO薄膜光电性能和直接利用低速率生长的薄膜特性相当或更好,并且极大地降低了薄膜生长时间。 Molybdenum-doped indium oxide(IMO) thin films are deposited at 350 ℃ with a growth rate varying in the range of 0.01-0.04 nm by the reactive electron beam vapor technique,and the microstructure,optical and electrical properties of the IMO films are investigated in detail.High purity In2O3:MoO3 ceramic targets and oxygen gas are used as source materials.Firstly,a 30 nm-thickness IMO buffer layer is fabricated on glass substrate by electron beam vapor deposition at the low growth rate of 0.01 nm/s.Secondly,a 50 nm-thickness IMO film is fabricated on the buffer layer via the same deposition technique at relatively higher growth rate of ~0.04 nm/s.The IMO film performances are as follows:resistivity,ρ,is ~2.5×10^-4 Ω cm,sheet resistance,Rs,is ~22.5 Ω,concentration,n,is ~5.8×10^20 cm^-3,electron mobility,μ is ~47.1 cm2V^-1s^-1,the average transmittance in the visible and near infrared region,Ta,is ~80%.The optical and electrical properties of the IMO films obtained with buffer layer are equivalent to/or superior to those of the films at low growth rate.In addition,the buffer-layer reduces effectively the process time.
出处 《光电子.激光》 EI CAS CSCD 北大核心 2009年第12期1599-1601,共3页 Journal of Optoelectronics·Laser
基金 国家"973"重点基础研究资助项目(2006CB202602 2006CB202603) 天津市应用基础及前沿技术研究计划资助项目(09JCYBJC06900) 天津市科技攻关资助项目(06YFGZGX02100)
关键词 电子束蒸发技术 In2O3:Mo(IMO)薄膜 高迁移率 太阳电池 electron beam deposition In2O3:Mo(IMO) thin films high mobility solar cells
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