摘要
本文以作者在温控水/有机两相及温控非水液/液两相催化领域的研究工作为主线,对这一领域的研究进展做一评述,重点是环绕经典水/有机两相催化体系存在"应用范围受底物水溶性限制"的根本问题展开。特别是对"温控相转移催化"做了较为详细的介绍,同时,按体系介质不同,对氟两相体系、PEG两相体系、离子液体两相体系等非水液/液两相体系以及温控相分离催化分别做了阐述。
This paper reviews the recent progress in biphasic catalysis based on our research in the fields of thermoregulated aqueous-organic biphasic catalysis and thermoregulated non-aqueous liquid-liquid biphasic catalysis, in which the authors aim at the solution to the limitation in the application of the classic aqueous-organic biphasic catalysis due to the low water-solubility of the substrates. Especially, the authors discuss the thermoregulated phase transfter catalysis （TRPTC） in detail. Moreover, various non-aqueous biphasic systems clarified by the reaction mediums, including the fluorous biphasic system, the PEG biphasic system, the ionic liquid biphasic system, as well as the thermoregulated phase-separable catalysis have been also reviewed.
出处
《化学进展》
SCIE
CAS
CSCD
北大核心
2010年第7期1295-1309,共15页
Progress in Chemistry
基金
国家自然科学基金项目(No.20976024
20476015
20376013
29792074)资助
我校离退休人员科研专项基金(DUTTX2009101)资助
关键词
均相催化多相化
液/液两相催化
温控相转移催化
水/有机两相催化
非水液/液两相催化
催化剂分离回收
multiphase homogeneous catalysis
liquid/liquid biphasie catalysis
thermoregulated phase transfer catalysis
aqueous/organic biphasic catalysis
non-aqueous liquid/liquid biphasic catalysis
catalyst separation and recycling
