期刊文献+

BiFeO_3掺杂对CaCu_3Ti_4O_(12)陶瓷结构和介电性能的影响 被引量:1

Effects of BiFeO_3 doping on the structure and dielectric properties of CaCu_3Ti_4O_(12) ceramics
下载PDF
导出
摘要 采用固相反应法制备了BiFeO3掺杂的CaCu3Ti4O12(CCTO)陶瓷,研究了BiFeO3掺杂量对CCTO陶瓷的烧结性能、晶体结构和介电性能的影响。结果表明,BiFeO3掺杂改善了CCTO陶瓷的烧结性能。随BiFeO3掺杂量的增加,CCTO陶瓷的晶格常数和εr均先增大而后减小;而tanδ先几乎不变而后增大。当x(BiFeO3)为0.5%,1040℃烧结的CCTO陶瓷样品在1kHz时具有巨介电常数(εr=14559)和较低的介质损耗(tanδ=0.12)。 BiFeO3 doped CaCu3Ti4O12(CCTO) ceramics were prepared using the solid state reaction method.The effects of BiFeO3 doping amount on the sintering characteristic,crystal structure and dielectric properties of CCTO ceramics were investigated.The results show that the sintering characteristic of CCTO ceramics is improved by BiFeO3 doping.With the increase of BiFeO3 doping amount,the lattice constants and relative permittivity of CCTO ceramics increase at first,then gradually decrease.However,dielectric loss changes little first,and then increases while the BiFeO3 doping amount increases.With the 0.5%(mole fraction) BiFeO3 doping,the CCTO ceramic sample sintered at 1 040℃ possesses giant permittivity(εr=14559) and low dielectric loss(tanδ=0.12) at 1 kHz.
出处 《电子元件与材料》 CAS CSCD 北大核心 2010年第3期8-11,共4页 Electronic Components And Materials
基金 福建省高等学校新世纪优秀人才支持计划资助项目(NoXSJRC2007-16) 福建省属高校资助项目(No2007F5002) 福州大学发展基金资助项目(No2007-XQ-01)
关键词 CACU3TI4O12 BIFEO3 巨介电常数 固相反应法 CaCu3Ti4O12 BiFeO3 giant permittivity solid state reaction method
  • 相关文献

参考文献15

  • 1RAMIREZ A P,SUBRAMANIAN M A,GARDEL M,et al.Giant dielectric constant response in a copper-titanate[J].Solid State Commun,2000,115(15):217-220. 被引量:1
  • 2ADAMS T B,SINCLAIR D C,WEST A R.Giant barrier layer capacitance effects in CaCu3Ti4O(12) ceramics[J].Adv Mater,2002,14(18):1321. 被引量:1
  • 3SUBRAMANIAN M A,LI D,DUAN N,et al.High dielectric constant in ACu3Ti4O(12) and ACu3Ti3FeO12 phases[J].J Solid State Chem,2000,151(2):323-325. 被引量:1
  • 4FU D S,TANIGUCHI H,TANIYAMA T,et al.Origin of giant dielectric response in nonferroelectric CaCu3Ti4O(12):inhomogeneous conduction nature probed by atomic force microscopy[J].Chem Mater,2008,20:1694-1698. 被引量:1
  • 5FANG T,SHIAU H K.Mechanism for developing the boundary barrier layers of CaCu3Ti4O(12)[J].J Am Ceram Soc,2004,87(11):2072-2079. 被引量:1
  • 6FENG L X,TANG X M,YAN Y Y.Decrease of dielectric loss in CaCu3Ti4O(12) ceramics by La doping[J].Phys Status Solidi,2006,203(4):22-24. 被引量:1
  • 7YAN Y Y,JIN L,FENG L X,et al.Decrease of dielectric loss in giant dielectric constant CaCu3Ti4O(12) ceramics by adding CaTiO3[J].Mater Sci Eng,2006,130(1/2/3):146-150. 被引量:1
  • 8CHUNG S H,CHOI S Y,YAMAMOTO T,et al.Site-selectivity of 3d metal cation dopants and dielectric response in calcium copper titanate[J].Appl Phys Lett,2006,88(9):091917. 被引量:1
  • 9慕春红,刘鹏,贺颖,张丹,孟玲,边小兵.Fe掺杂CaCu_3Ti_4O_(12)陶瓷的介电性能与弛豫特性研究[J].物理学报,2008,57(4):2432-2437. 被引量:13
  • 10VALANT M,AXELSSON A K,ALFORD N.Peculiarities of a solid-state synthesis of multiferroic polycrystalline BiFeO3[J].Chem Mater,2007,19:5431-5436. 被引量:1

二级参考文献36

共引文献15

同被引文献22

引证文献1

二级引证文献2

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部