摘要
A thermodynamic assessment of the Cu-Cd system has been carried out by CALPHAD technique.The liquid phase, FCC_A1(Cu)and HCP_A3(Cd)terminal phases are described by a simple substitutional model,their excess Gibbs energy is formulated with the Redlich-Kister expression.The system contains four intermediate compounds,includingβ(Cu2Cd),γ(Cu4Cd3), δ(Cu5Cd8)andε(Cu3Cd10).Theδphase is described by a two-sublattice model and the other three intermediate phases are treated as stoichiometric phases.The optimization is carried out in the Thermo-Calc package.A set of self-consistent thermodynamic parameters are obtained.The calculated phase diagram and thermodynamic properties agree well with the available experimental data.
A thermodynamic assessment of the Cu-Cd system has been carried out by CALPHAD technique.The liquid phase, FCC_A1（Cu）and HCP_A3（Cd）terminal phases are described by a simple substitutional model,their excess Gibbs energy is formulated with the Redlich-Kister expression.The system contains four intermediate compounds,includingβ（Cu2Cd）,γ（Cu4Cd3）, δ（Cu5Cd8）andε（Cu3Cd10）.Theδphase is described by a two-sublattice model and the other three intermediate phases are treated as stoichiometric phases.The optimization is carried out in the Thermo-Calc package.A set of self-consistent thermodynamic parameters are obtained.The calculated phase diagram and thermodynamic properties agree well with the available experimental data.
