摘要
The title complex,[（BBI）Mn（BDC）]n 1（BBI = 2,2＇-bisbenzimidazole（C14H10N4）,BDC=benzene-1,3-dicarboxylate dianion（C8H10O4））,crystallizes in the monoclinic system,space group C2/c,with a=17.822（8）,b=16.181（7）,c=13.355（6）A,β=92.112（5）°,V=3848.67（304）A^3,Z=8,C22H14MnN4O4,Mr=453.31,Dc=1.565 g/cm^3,F（000）=1848,μ=0.725 mm^-1,S=1.000,the final R=0.0310 and wR=0.0589.1 contains hydrogen bonds and π-π stacking interactions between the neighboring aryl-ring of BBI＇s,which helps to form a three-dimensional crystal structure.
The title complex,[（BBI）Mn（BDC）]n 1（BBI = 2,2＇-bisbenzimidazole（C14H10N4）,BDC=benzene-1,3-dicarboxylate dianion（C8H10O4））,crystallizes in the monoclinic system,space group C2/c,with a=17.822（8）,b=16.181（7）,c=13.355（6）A,β=92.112（5）°,V=3848.67（304）A^3,Z=8,C22H14MnN4O4,Mr=453.31,Dc=1.565 g/cm^3,F（000）=1848,μ=0.725 mm^-1,S=1.000,the final R=0.0310 and wR=0.0589.1 contains hydrogen bonds and π-π stacking interactions between the neighboring aryl-ring of BBI＇s,which helps to form a three-dimensional crystal structure.
基金
supported by Jilin Normal University
