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Enzymatic saccharification of cellulose using an ionic liquid [Amim] [COOH] pretreatment

Enzymatic saccharification of cellulose using an ionic liquid [Amim] [COOH] pretreatment
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摘要 In this study we used l-allyl-3-methyl imidazole formate ([Amim][COOH]) as ionic liquid to pre-treat the cellulose and determined the rate of polymerization and enzymatic hydrolysis. The results showed that pretreatment with ([Amim][COOH]) significantly decreased the cellulose polymerization. As the pretreatment temperature went up, the enzymatic hydrolysis rate was first increased and then decreased The maximal enzymatic hydrolysis rate was achieved when the pretreatment temperature was 90 ℃. Under the ultrasonic condition, the initial rate of enzmatic hydrolysis for the ionic liquid-treated cellulose was up to 11.10 gL-1h-1, which was 33% increase compared to the untreated cellulose. Scanning Electronic Microscopy (SEM) and Fourier Transform Infrared-Raman Spectroscop (FT-IR) analysis showed that ionic liquidtreated cellulose started to depolymerize. In addition, the cr3'stallinity of the cellulose was significantly decreased after pretreatment with ionic liquid.
出处 《Journal of Energy and Power Engineering》 2009年第9期49-53,共5页 能源与动力工程(美国大卫英文)
关键词 ionic liquid cellulose: pretreatment: enzymatic hydrolysis: ultrasonic 预处理温度 纤维素酶 离子液体 羧基 扫描电子显微镜 糖化 红外光谱 傅立叶变换
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