摘要
The title complex [CpIr{N（Ph2PS）2}（N3）]（N（Ph2PS）2=bis（diphenylthiophosphoryl）amide,Cp=pentamethylcyclopentadienyl） has been prepared and characterized by X-ray diffraction analysis.It crystallizes in monoclinic,space group P21/n with a=11.6946（1）,b=18.9273（2）,c=15.7859（1）,β=105.731（1）°,V=3363.29（5）3,Z=4,Mr=817.92,Dc=1.615g/cm3,μ（MoKα）=4.219 mm-1,F（000）=1624,S=1.028,the final R=0.0355 and wR=0.0848 for 5987 observed reflections with Ⅰ〉2σ（Ⅰ） and 363 variables.The molecular structure of 1 consists of discrete monomeric molecule with a distorted octahedral configuration around the iridium atom, having a Cp^＊ ring at one face and bonded with a chelating bis（diphenylthiophosphoryl）amide group as well as a terminal azido ligand. The average Ir-S and Ir-N bond lengths are 2.416（1） and 2.121 （5） A, respectively.
The title complex [CpIr{N（Ph2PS）2}（N3）]（N（Ph2PS）2=bis（diphenylthiophosphoryl）amide,Cp=pentamethylcyclopentadienyl） has been prepared and characterized by X-ray diffraction analysis.It crystallizes in monoclinic,space group P21/n with a=11.6946（1）,b=18.9273（2）,c=15.7859（1）,β=105.731（1）°,V=3363.29（5）3,Z=4,Mr=817.92,Dc=1.615g/cm3,μ（MoKα）=4.219 mm-1,F（000）=1624,S=1.028,the final R=0.0355 and wR=0.0848 for 5987 observed reflections with Ⅰ〉2σ（Ⅰ） and 363 variables.The molecular structure of 1 consists of discrete monomeric molecule with a distorted octahedral configuration around the iridium atom, having a Cp^＊ ring at one face and bonded with a chelating bis（diphenylthiophosphoryl）amide group as well as a terminal azido ligand. The average Ir-S and Ir-N bond lengths are 2.416（1） and 2.121 （5） A, respectively.
基金
supported by the National Natural Science Foundation of China
the Program for New Century Excellent Talents in University (20771003 and NCET-06-0556)
