摘要
将自制的2种疏水性复合电极(M-PTFE,M=Ni、Zn)分别应用于环己醇的电化学氧化和环己酮的电化学还原,测定了不同条件下的循环伏安曲线和电极稳定性,结果表明环己醇电化学氧化的转化率达92.5%和环己酮电化学还原的转化率达94.6%。
Hydrophobic metal-poly （tetrafluoroethylene）（M-PTFE, M = Ni or Zn） composite electrode is prepared and used for electrochemical oxidation of cyclohexanol and electrochemical reduction of cyclohexanone. The electrochemical characteristics such as cyclic voltammogram and stability are determined under different conditions. The results show that the conversion ratio of electrochemical oxidation of cyclohexanol can be 92.5 %, and the conversion ratio of electrochemical reduction of cvclohexanone, 94.6 %.
出处
《现代化工》
CAS
CSCD
北大核心
2010年第1期44-46,48,共4页
Modern Chemical Industry
基金
福建省教育厅A类面上项目(JA08034)
关键词
PTFE复合电极
环己醇
环己酮
电化学氧化还原
PTFE composite electrode
cyclohexanol
cyclohexanone
electrochemical oxidation-reduction
