摘要
根据黏弹性表面活性剂(VES)理论,研制一种性能优良的甜菜碱类变黏分流酸,分析其胶束结构特点和变黏性能,考察剪切速率对油酸酰胺丙基甜菜碱质量分数、pH值和不同温度下变黏分流酸流变性的影响,探讨pH值对胶束结构的影响,得出变黏分流酸的变黏机制。结果表明:油酸酰胺丙基甜菜碱在10%HC l中为球型胶束,在5%HC l中为球型-棒型过渡类型和棒状胶束,在2%HC l中为蠕虫状胶束;变黏分流酸随着酸液质量分数降低表观黏度逐渐增加,当油酸酰胺丙基甜菜碱质量分数大于临界胶束浓度(wcm c)时,变黏分流酸增黏后具有剪切稀释的黏弹流体特点;变黏分流酸在酸化过程中压力有先上升后下降的趋势,发生液流转向进入中低渗层,对储层无伤害。
Based on visco elastic surfactant theory, a new variable viscosity diverting acid （VVDC） with good performance was developed, and its micelle structure characteristics and viscosity variation property were analyzed. The influence of shear rate on the concentration of oleic amide propyl betaine, pH and rheological property of VVDC for different temperature was studied. The influence of the pH on micelle structure was discussed, and the viscosity variation mechanism of VVDC was ob- tained. The results show that the micelle structures of VVDC in the HCl of 10% , 5% , 2% （mass fraction） are globular, rod and the transitional form between globular and rod, and wormlike respectively. The apparent viscosity of VVDC increases with the acid concentration decreasing, and it has the dilution shearing feature when the oleic amide propyl betaine concentration is higher than the critical micelle concentration. During the acidizing process, the pressure of VVDC is reduced after increasing. And the flow of acid turned into the low-medium permeability reservoir, which does no harm to the reservoir.
出处
《中国石油大学学报（自然科学版）》
EI
CAS
CSCD
北大核心
2009年第6期136-141,共6页
Journal of China University of Petroleum(Edition of Natural Science)
基金
国家科技重大专项(2008ZX05022)
关键词
甜菜碱
变黏分流酸
流变性
变黏机制
岩心流动
betaine
variable viscosity diverting acid
rheological property
viscosity variation mechanism
core flow
