摘要
综述了国内外双环硝胺类含能化合物的合成进展,主要包括醛胺缩合法合成双环[3.3.1]壬烷衍生物、乌洛托品与亲电试剂反应合成双环[3.3.1]壬烷衍生物、以及含单、双环硝基脲硝胺类含能化合物的合成方法。指出含有单、双环硝基脲的硝胺类含能化合物具有非常高的密度,适合于作为高能量密度材料的基础单元结构;双环[3.3.1]壬烷衍生物合成中的醛胺缩合法为八元双环含能化合物的合成提供了新途径。
The current situation of investigation of bicyclic nitramine energetic compounds were reviewed, including synthesis of ring-bridged [ 3.3. 1 ] nonane via formaldehyde-ammonia reaction, synthesis of ring-bridged [ 3.3.1 ] nonane through reaction of urotropine with electrophilic reagents, and synthesis of bicyclic mono-and dinitrourea compounds. Both the mono- and dinitrourea compounds have inherently high densities, and are suitable for an ideal base structure in formulation of compounds. Formaldehyde-ammonia condensation reaction taking urea as primary material, is an attractive method of synthesizing the precursor of 8-membered ring nitramine energetic compounds.
出处
《应用化工》
CAS
CSCD
2009年第12期1802-1806,共5页
Applied Chemical Industry
基金
国防973项目子专题(613740202)