摘要
以丙酮和甲醇(体积比为3:1)为溶剂,1,2-二胺氧乙烷双缩5-溴水杨醛(H2L)与乙酸铜反应,制备了一种新型Schiff碱乙酸铜(Ⅱ)配合物,其结构经元素分析,1H-NMR,IR,TG-DTA及UV表征。结果表明,新型Schiff碱是一种四齿配体,配合物的可能结构式为[Cu(C16H12Br2N2O4)]2。
A novel Cu（Ⅱ）acetate monohydrate complex was prepared from Cupric（II）acetate and 4,4 -Dibromo-2,2 -[ethylenedioxybis（nitrilomethylidyne）]diphenol（H2L）in the mixed solvents of acetone and methanol（V∶V=3：1）.The structure was characterized by elemental analysis,1H-NMR,IR,TG-DTA and UV.The novel Schiff Base was a good tetradentate N2O2-donating ligand,and the structural formula of the complex was suggested as [Cu（C16H12Br2N2O4）]2.
出处
《滁州学院学报》
2009年第5期119-121,共3页
Journal of Chuzhou University
基金
滁州学院2008年度青年基金资助项目(2008kj002Q)
安徽省应用化学省级重点学科建设项目(200802187C)
