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A Comparative Study of Hydrophilic Modification of Polypropylene Membranes by Remote and Direct Ar Plasma

A Comparative Study of Hydrophilic Modification of Polypropylene Membranes by Remote and Direct Ar Plasma
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摘要 Surface modification of polypropylene membrane by argon (Ar) plasma-induced graft polymerization with hydrophilic monomer [acrylic acid (AA) in this work] was investigated. It was found that both the distance of the membrane from the Ar plasma center and the plasma power had a strong influence on the surface modification, hydrophilieity and graft yield (GY) of the treated membrane. Results suggest that remote plasma treatment with a proper sample position, plasma power and graft polymerization leads to a membrane surface with not only less damage, but also more permanent hydrophilicity, than direct plasma treatment does. By analyzing the morphology and the chemical composition of the membrane surface by scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS), as well as Fourier transform infrared attenuated total reflection spectroscopy (FTIR-ATR) respectively, a possible mechanism was tentatively revealed. Surface modification of polypropylene membrane by argon (Ar) plasma-induced graft polymerization with hydrophilic monomer [acrylic acid (AA) in this work] was investigated. It was found that both the distance of the membrane from the Ar plasma center and the plasma power had a strong influence on the surface modification, hydrophilieity and graft yield (GY) of the treated membrane. Results suggest that remote plasma treatment with a proper sample position, plasma power and graft polymerization leads to a membrane surface with not only less damage, but also more permanent hydrophilicity, than direct plasma treatment does. By analyzing the morphology and the chemical composition of the membrane surface by scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS), as well as Fourier transform infrared attenuated total reflection spectroscopy (FTIR-ATR) respectively, a possible mechanism was tentatively revealed.
出处 《Plasma Science and Technology》 SCIE EI CAS CSCD 2009年第5期576-581,共6页 等离子体科学和技术(英文版)
关键词 remote plasma polypropylene membrane hydrophilic modification graftingpolymerization remote plasma, polypropylene membrane, hydrophilic modification, graftingpolymerization
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