摘要
离子液体作为潜在的"绿色"溶剂,具有许多传统溶剂无法比拟的优异性能,在有机合成、催化、液液分离和萃取等领域引起了广泛的研究。而在离子液体领域无机材料的制备是一个较新的发展分支,已利用其合成出多种具有独特结构和性能的无机材料。本文就离子液体在无机材料制备方面的应用及发展趋势进行了综述。目前,对于制备无机材料,离子液体主要是作为电解液、表面活性剂或溶剂,本文介绍了其在应用中的优缺点。并指出该领域未来的发展趋势是离子热合成和集模板-溶剂-反应物于一身的离子液体反应。
As a potential ＂green＂ solvents, room-temperarture ionic liquids （RTILs） have received much attention, and significant progress has been made in their applications for organic synthesis, catalysis, liquid-liquid separations, and extractions. However, inorganic synthesis is a relatively new branch in the ionic liquid community which shows that ILs have great advantage over the traditional solvents in the synthetical process and provide a new route for inorganic synthesis. In recent years, a number of inorganic materials with unique structures and properties have been synthesized from ionic liquids. This paper reviews the status and application of ionic liquids in the inorganic synthesis. Inoic liquids at present are mainly used as electrolytes, surfactants or solvents, the advantages and disadvantages of ionic liquids in the application are analyzed. Ionothermal synthesis and all-in-one ionic liquids are the development trends in the synthesis of inorganic materials in the future.
出处
《化学进展》
SCIE
CAS
CSCD
北大核心
2009年第10期2077-2083,共7页
Progress in Chemistry
关键词
离子液体
无机材料
离子热合成
反应性离子液体
ionic liquids（ILs）
inorganic materials
ionothermal synthesis
all-in-one ionic liquids
