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四氢硫芴和六氢硫芴的合成 被引量：2

Synthesis of Tetrahydrodibenzothiophene and Hexahydrodibenzothiophene
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摘要 以2-溴环己酮及苯硫酚为原料,经Tilak反应,然后环化合成了四氢硫芴(1);在三氟乙酸与锌粉存在下1于室温加氢制得六氢硫芴,其结构经1H NMR和GC-MS确证。 Tetrahydrodibenzothiophene （ 1 ） was synthesized from 2-bromocyclohexanone and thiophenol by the Tilak reaction and then cyclization. 1 was reduced in the presence of trifluoroacetic acidand Zn to obtain hexahydrodibenzothiophene. The structures were confirmed by 1H NMR and GC- MS.
作者 杜学梅 李翔 王安杰
机构地区 大连理工大学精细化工国家重点实验室 大连理工大学辽宁省高校石油化工技术与装备重点实验室
出处 《合成化学》 CAS CSCD 北大核心 2009年第5期622-623,627,共3页 Chinese Journal of Synthetic Chemistry
基金 国家自然科学基金重点基金资助项目(20333030) 国家自然科学基金青年基金资助项目(20503003) 国家自然科学基金资助项目(20773020) 教育部"111"引智工程资助项目
关键词 四氢硫芴 六氢硫芴 加氢脱硫 合成 tetrahydrodibenzothiophene hexahydrodibenzothiophene hydrodesulfurization synthesis
分类号 O625.15 [理学—有机化学] TQ247.2 [理学—化学]
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参考文献10

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同被引文献12

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合成化学
2009年 第5期

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