摘要
The title compound,[Ag4(L)4](PMBS)4·2H2O (1),where L=2,5-bis(4-pyridyl)-3,4-diaza-2,4-hexadiene,PMBS =p-methylbenzenesulfonate was synthesized and its crystal structure was determined by X-ray diffraction structure analysis. The crystal is of triclinic,space group P1 with a=0.820 3(2) nm,b=1.322 7(3) nm,c=2.061 0(3) nm,α=76.155(2)°,β=78.651(4)°,γ=89.993(3)°,V=2.126 2(8) nm3,Z=2,Dc=1.644 g·cm-3,F(000)=1 068,R=0.052 4,wR=0.113 6. The Ag atoms are linear coordinated by two N atoms of two L ligands,while the p-methylben-zenesulfonate molecules are included in the lattice and connected to [Ag(L)]n by hydrogen bonding interactions to form a three-dimensional supramolecular structure.
The title compound, [Ag4（L）4]（PMBS）4·2H2O （1）, where L=2,5-bis（4-pyridyl）-3,4-diaza-2,4-hexadiene, PMBS =p-methylbenzenesulfonate was synthesized and its crystal structure was determined by X-ray diffraction structure analysis. The crystal is of trielinic, space group P1 with a=0.820 3（2） nm, b=1.3227（3） nm, c=2.061 0（3） nm, α=76.155（2）°,β=78.651 （4）°, γ=89.993（3）°, V=2.126 2（8） nm^3, Z=2, Dc= 1.644 g· cm^-3, F（000）= 1 068, R =0.052 4, wR=0.113 6. The Ag atoms are linear coordinated by two N atoms of two L ligands, while the p-methylben- zenesulfonate molecules are included in the lattice and connected to [Ag（L）]n by hydrogen bonding interactions to form a three-dimensional supramolecular structure. CCDC： 727587.
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
2009年第7期1312-1315,共4页
Chinese Journal of Inorganic Chemistry
基金
湖南省重点学科建设项目
湖南省青年骨干教师基金(2008)
衡阳师范学院青年骨干教师基金(2007)
衡阳市科技局资助项目(No.2007KJ004)资助项目
关键词
银配合物
晶体结构
氢键
荧光性质
Ag（Ⅱ） complex
crystal structure
hydrogen bond
luminescent property
