摘要
合成了４，４′，４″，４—四氯酞菁合铁（Ⅱ），并进行了表征，用不可逆吸附法制备了以该化合物为修饰物的化学修饰电极，研究了异烟肼在该化学修饰电极上的电化学行为，发现该配合物修饰电极对异烟肼的氧化有显著的电催化作用，并提出了相应的电催化机理。
Ferrous 4,4′,4″,4 tetrachloro phthalocyanine was synthesized and characterized. Its chemically modified electrode was prepared. The electrochemical behaviors of the FeTCPc CME were studied. The electrocatalytical Oxidation of isonicotinylhydrazine was investigated. It was proposed that Fe 2+ /Fe + redox sites at the FeTCPc CME should be transported electrons from the absorbed isonicotinylhydrazine molecules to the glass carbon electrode to electrocatalytically oxide isonicotinylhydrazine.
出处
《湖北农学院学报》
1998年第2期162-165,共4页
Journal of Hubei Agricultural College
关键词
异烟肼
酞菁
化学修饰电极
电催化
isonicotinylhydrazine
phthalocyanine
chemically modified electrode
electrocatalysis
