摘要
以2,2-双二茂铁基丙烷为原料,经两步酰化合成6-丙酰基-6′-丁酰基(2,2-双二茂铁基丙烷),酰化产物分别以LiAlH4和Zn-Hg作为还原剂进行还原,得到相应的6,6′-不同α-羟烷基和6,6′-不同烷基取代的衍生物,利用元素分析、IR及1H NMR对化合物结构进行了表征.
In this paper, acylation of 2,2-bisferrocenylpropane is carried out with acid anhydride in the presence of boron trifluoride and methylene chloride. 6-propionyl-6＇-butyryl（2,2-bisferrocenylpropane） is prepared by the Friedel-Crafts reaction and reduced to the corresponding α-hydroxyalkyl and alkyl deriva- tives of 2,2-bisferrocenylpropane with LiAlH4 and Zn（Hg）/HC1. The structures of these compounds are characterized by elemental analysis,IR spectrum and 1HNMR spectra.
出处
《内蒙古师范大学学报（自然科学汉文版）》
CAS
2009年第3期296-298,303,共4页
Journal of Inner Mongolia Normal University(Natural Science Edition)
基金
内蒙古自然科学基金资助项目(200711020204)
关键词
2
2-双二茂铁基丙烷
酰化
还原
表征
合成
2,2-bisferrocenylpropane
acylation
reduction
characterization
synthesis
