摘要
研究了基于同位素稀释质谱法原理准确测定锂同位素丰度的方法,编制方法的求解方程。对样品和稀释剂进行了纯化,用ICP发射光谱测定了其杂质元素总量,配制样品和稀释剂溶液。用质量法配制样品和稀释剂的混合溶液,用热电离质谱法测量了同位素丰度比值。计算得到方法的系统偏差校正因子为0.992 0。通过测量IRMM 016锂同位素标准物质得到的校正因子与本方法的校正因子一致,验证了方法的可靠性。用校正因子校正样品和稀释剂的同位素丰度比的测量值,得到准确值。同时,评定了方法的不确定度。结果显示,在95%的置信水平下,应用这种方法测定锂样品同位素丰度比值,其相对扩展不确定度为0.26%。
A method for determination of isotopic abundances of lithium based on the principle of isotopic dilution mass spectrometry was studied. Both the sample and the spike were purified. Impurities in the sample were analyzed by ICP-AES. The abundance ratios of ^6Li/^7Li were measured by thermal ionization mass spectrometry. The correction factor for systematic deviation is iteratively calculated to be 0. 992 0 and is in good agreement with that obtained with lithium isotope reference material IRMM 016. The isotopic ratio of the sample is finally obtained by correction of the IDMS measured value with the correction factor. At 95% confidence level the relative expanded uncertainty of the present method for determination of lithium isotopic abundance ratio is estimated to be 0.26 %.
出处
《核化学与放射化学》
CAS
CSCD
北大核心
2009年第2期79-83,共5页
Journal of Nuclear and Radiochemistry
关键词
同位素稀释质谱法
锂同位素
系统偏差校正
isotopic dilution mass spectrometry （IDMS）
lithium isotope
calibration of system deviation
