摘要
以乙酸和环己醇为原料,自制的新型固体超强酸S O42-/Sb2O3/SiO2作催化剂,催化合成乙酸环己酯。反应结果表明,最优化条件是:n(乙酸):n(环己醇)=1.0:1.2,催化剂用量为0.8g,反应温度为145℃～160℃,反应时间为4h,酯化率可达94.7%。产品用折光率和红外光谱进行表征。
Cyclohexyl acetate was synthesized from acetic acid and cyclohexanol catalyzed by the new SO4^2-/Sb2O3 /SiO2 catalys made by the researcher himself. The experiment results showed that the optimum reaction conditions were as follows： when the molar ratio of cyclohexanol to acetic acid was 1：1.2, the dosage of SO4^2-/Sb2O3 /SiO2 was 0.8g and temperature of reactionis was 145-160℃, reflux time was 4 hour. The esterification yield reached to 94.7%. The product was characterized by refractive index and IR.
出处
《铜仁学院学报》
2009年第2期84-87,105,共5页
Journal of Tongren University
