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乙烯聚合铬系催化剂研究进展 被引量:9

ADVANCES IN STUDY OF CHROMIUM BASED CATALYST FOR ETHYLENE POLYMERIZATION
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摘要 综述了用于乙烯聚合生成聚乙烯树脂的铬系催化剂40多年来的发展历程及最新进展,介绍了各种不同体系的含铬催化剂的制备方法、技术特点以及研究现状。认为铬系催化剂在聚乙烯工业生产中仍将起到重要作用。 ? This paper reviewed the preparation methods,technological features and recent advances of the chromium based catalysts developed at home and abroad.From the incisive analysis based on the documents collected,it was concluded that chromium based catalyst would continue to play an important role in polyethylene industry in the coming years,though there existed other catalyst systems such as metallocene catalyst that gained momentum.
出处 《石化技术》 CAS 1998年第1期58-61,共4页 Petrochemical Industry Technology
关键词 铬系催化剂 乙烯聚合 聚乙烯 chromium based catalyst, ethylene, polymerization
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  • 1吴俞翔,张海坤,董奇,于永玲,唐岩,程瑞华,刘柏平.S-2铬系催化剂催化乙烯与1-己烯共聚合[J].合成树脂及塑料,2010,27(2):1-4. 被引量:4
  • 2马琳,高宏,陈卫民,倪前龙,马莉.铬系催化剂的制备与分析监控[J].上海化工,2005,30(6):30-34. 被引量:3
  • 3[4]Benham B A, Smith P D, Hsieh E T, et al. Catalysts for high-temperture slurry polymerization of ethylene[J].J Macromol Sci Chem, 1988,25(3):259. 被引量:1
  • 4王洪涛,石志俭,王如恩,等.负载型钛化的铬催化剂、制法及在乙烯聚合中的应用:中国.101173013[P].2008-05-07. 被引量:3
  • 5John C Chadwick, Thomas Garoff, John R Severn. Tailor-Made Polymers: Traditional Heterogeneous Catalysts[M]. NewYork: John Wiley, 2008: 60-72. 被引量:1
  • 6Zahra Mohamadnia, Ebrahim Ahmadi, Mehdi Nekoomanesh, et al. Effect of support structure on the activity of Cr/nanosilica catalysts and themorphology of prepared polyethylene[J]. Society of Chemical Industry, 2010, 59 (7) : 945-953. 被引量:1
  • 7Haruhiko lkeda, Takashi monoi, Yasuaki sasaki. Performance of the Cr[CH(SiMe3)2]3/SiO2 catalyst for ethylene polymerization compared with the performance of the phillips catalyst[J]. Journal of Polymer SciencePartA: PolymerChemistry, 2002, 41 (3): 413-419. 被引量:1
  • 8Takashi Monoi, Yasuaki Sasaki. Silica-supported Cr[N(SiMe3)2]3/ isobutylalum-oxane catalyst for selective ethylene trimerization[J]. Journal of Molecular Catalysis A: Chemical, 2002, 187( 1 ): 135-141. 被引量:1
  • 9Varkeya Saji P, Lobo Raul F, Theopold Klaus H. Zeolite MCM-22 supported heterogeneous chromium catalyst for ethylene polymerization[J]. Catalysis Letters, 2003, 88 (3-4): 227-229. 被引量:1
  • 10Fang Yuwei, Xia Wei, He Man, et al. Novel SiO2-supported chromium catalyst bearing new organo-siloxane ligand for ethylene polymerization[J]. Journal of Molecular Catalysis A: Chemical, 2006, 247 (1-2): 240-247. 被引量:1

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