摘要
金属-配体间的配位作用是超分子化学中最重要的相互作用之一,寡聚吡啶配体可以与许多过渡金属离子配位,形成具有独特磁、光物理和电化学性质的过渡金属络合物,因此联三吡啶配体的合成及其过渡金属络合物性能研究引起化学家的广泛关注.综述了联三吡啶配体及其衍生物的合成方法,主要包括成环缩合反应、过渡金属催化的偶联反应以及其它方法,并选取具有代表性的实例对联三吡啶配体的结构和合成方法进行详细地阐述.
Metal-ligand coordination is one of the most important interactions used in supramolecular chemistry. Oligopyridine ligands can coordinate with many transition metal ions to form stable complexes with interesting magnetic, photophysical and electrochemical properties, so the synthetic methodologies for terpyridine ligands and their transition metal complexes have been attracting considerable attention. This review summarizes the synthetic methodologies for terpyridine and its derivatives. The reactions are mainly classified into two kinds： ring-forming condensation and transition metals catalyzed cross-coupling. Meanwhile, some other methods are also emphasized and a number of representative examples are selected to illustrate the ligand structures and synthetic methods.
出处
《有机化学》
SCIE
CAS
CSCD
北大核心
2009年第4期504-516,共13页
Chinese Journal of Organic Chemistry
基金
国家自然科学基金(Nos.50473016,20521202)
北京自然科学基金(No.2093033)资助项目.
关键词
联三吡啶配体
合成
成环缩合反应
偶联反应
terpyridine ligand
synthesis
ring-forming condensation reaction
cross-coupling reaction
