期刊文献+

采用唯象理论研究光聚合动力学

Investigating the Kinetics of Photopolymerization with Phenomenological Theory
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摘要 文章探讨紫外光固化的自加速现象,并用唯象理论从数学上作出阐述、考察了单体种类,光引发剂种类对动力学参数的影响,并对不同条件下该模型的参数进行了计算。结果表明,该数学模型能很好地量化在不同条件下光聚合反应的变化。 The paper investigated kinetics in UV-Curing by DPC and used phenomenological theory to interpret the autoacceleration behavior of photopolymerization. The influence of defferent photoinitiators and monomers were dicussed. The parameters of kinetics were obtained by the simulation analysis. As a consequence, the photopolymerization could be investigated quantitatively by this means.
作者 叶国东
出处 《广东化工》 CAS 2009年第4期17-18,共2页 Guangdong Chemical Industry
基金 广州医学院博士启动基金
关键词 光聚合 数学模型 紫外 动力学 自加速 photopolymerization mathematical model UV kinetics autoacceleration
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参考文献3

  • 1Dietliker K. In Chemistry & Technology of UV&EB Formulation for Coating[J]. Inks&Paints, London: SITATechnology, Ed., 1991: 3. 被引量:1
  • 2Ye G D, Chen Y L. Low VOC bifunctional photoinitiator based on a-hydroxyalkylphenone structure[J]. Polymer, 2006, 47: 4603-4612. 被引量:1
  • 3Nicholas J T, Wu C H. Laser Flash Spectroscopic Investigation of Micellized Radical Pairs[J]. Direct Measurement of the Exit Rates of Micellized Radicals, JAm. Chem. SOC, 1995, 117: 11031-11032. 被引量:1

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