摘要
用Co2（CO）8与CH3CSNH2反应制得产物Ⅰ，又用Na2Fe（CO）4与Ⅰ反应制得产物Ⅱ（Ⅰ：Co3（μ3－S）（CO）7（CH3CSNH），Ⅱ：Co2Fe（μ3-S）（CO）7（CH3CSNH）．通过元素分析。IR、UV、1HNMR、MS表征并用X射线衍射法测得Ⅱ的单晶结构.该簇合物属三斜晶系、PT空间群，晶胞参数：a=0．9203（1），b=1．1296（2），c=1.1425（2）nm；α=116．40°（2），β＝101．92°（2），γ＝92．58°（1）；z＝2，V=1．2162nm3，Dc＝1．698cm3，μ＝21．89cm-1.结构分析表明，Co2FeS构三角锥分子骨架，所有CO均为端基配体，S1为面桥基配体，CH3CSNH为双齿配体，与Co、Fe形成五元环结构．
The Compound ⅠCo3(μ3-S) (CO)7 (CH3CSNH) was prepared by reaction of Co2(CO)8 with CH3CSNH2. Subsequently it was proposed with Na2Fe(CO)4 to give the compound Ⅱ Co2Fe(μ3-S) (CO)7(CH3CSNH). The compound Ⅰand Ⅱ have been char-acterized by elemental analysis, IR、UV、HNMR and MS spectrometties. The single crystal X-ray diffration show that the compound Ⅰand Ⅱ are of triclinic, belong to space group PT and the cell parameters as following: a = 0. 920 3(1), b= 1. 129 6(2), c = 1. 142 5(2) nm; α= 116. 40°(1), β=101. 92°(2), γ= 92. 58°(1 ); z= 2, V= 1. 216 2 nm3, Dc= 1. 698 cm3, μ= 21. 89 cm-1. The results suggcst that two con1P0u11tls all contain tetrahedral frameworks,all carbonyls arc terminal ligands and CH3CSNH as bidentate, in which S is birdging ligand,links up two cobalt to form a fivc-member ring.
出处
《分子科学学报》
CAS
CSCD
1997年第4期201-204,共4页
Journal of Molecular Science
基金
内蒙古自治区自然科学基金
