摘要
Using Nd:YAG second harmonic pulse (100 ps), the optical storage properties of two novel polyesters, poly [4'-bis (N, N-oxyethylene) imino-4-nitroazobenzene succinyl] and poly [2'-chloro-4'-bis (N, N-oxyethylene) imino-4-nitroazobenzene succinyl] have been studied by multiwave mixing. The high-order diffractions of the orientation gratings induced by anisotropy via the reorientation of nitroazobenzene groups and optical information storage with long-term stability have been realized by multiwave mixing in their films. Up to 3rd order forward diffraction was detected in two wave mixing, while up to 4th order backward diffraction was observed in degenerated four wave mixing. The recording mechanism was explained by the trans-cis-trans isomerization cycles of azobenzene groups. The isomerization of these azobenzene groups probably undergoes with inversion mechanism under the experimental conditions. The information recorded in these films has been kept for more than 6 months.
Using Nd:YAG second harmonic pulse (100 ps), the optical storage properties of two novel polyesters, poly [4'-bis (N, N-oxyethylene) imino-4-nitroazobenzene succinyl] and poly [2'-chloro-4'-bis (N, N-oxyethylene) imino-4-nitroazobenzene succinyl] have been studied by multiwave mixing. The high-order diffractions of the orientation gratings induced by anisotropy via the reorientation of nitroazobenzene groups and optical information storage with long-term stability have been realized by multiwave mixing in their films. Up to 3rd order forward diffraction was detected in two wave mixing, while up to 4th order backward diffraction was observed in degenerated four wave mixing. The recording mechanism was explained by the trans-cis-trans isomerization cycles of azobenzene groups. The isomerization of these azobenzene groups probably undergoes with inversion mechanism under the experimental conditions. The information recorded in these films has been kept for more than 6 months.
