摘要
在ｐＨ６００的ＨＡｃ－ＮａＡｃ缓冲溶液中，Ａｌ（Ⅲ）－铬偶氮酚ＫＳ在单扫示波极谱仪上可产生灵敏的二阶导数极谱波，Ｅｐ为－０４６Ｖ（υｓＳＣＥ）在７４０×１０－７～１３３×１０－５ｍｏｌ／Ｌ范围内，ｉｐ∝ＣＡｌ（Ⅲ）回归方程为ｉｐ＝３２３＋２１７ＣＡｌ（Ⅲ），γ＝０９９８４试验表明，该极谱波属络合物吸附波本法已用于人发中铝的测定。
In the buffer solution of acetic acid-sodium acetate(pH600),the sensitive adsorptive wave of complex of aluminium and chromazol KS was observed at -0.46V(υs.SCE)by single-sweep oscillopolarography.The height of second derivative wave is linearly related to the concentration of Al(Ⅲ) in the range of 7.40×10-7～133×10-5mol/LThe standard regression equation is ip=323+217CAl(Ⅲ),the correlaton coeffient γ=09984The method has been applied well to the determination of aluminium in hair.
出处
《广东工业大学学报》
CAS
1998年第1期15-18,共4页
Journal of Guangdong University of Technology
