High Diastereoselectivity in the Conjugate Addition of Functionalized Alcohols to a Chiral(E)-Nitroalkene

High Diastereoselectivity in the Conjugate Addition of Functionalized Alcohols to a Chiral(E)-Nitroalkene

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摘要 Modest to high diastereoselectivites have been observed in the conjugate addition of functionalized alcohols to chiral (E)-nitroalkene 1 depending on the presence of metal catalysts at low tempertwre. The resultS indicated that the anti-form had been preferred in all cases. Modest to high diastereoselectivites have been observed in the conjugate addition of functionalized alcohols to chiral (E)-nitroalkene 1 depending on the presence of metal catalysts at low tempertwre. The resultS indicated that the anti-form had been preferred in all cases.

作者 Qian CHENG Takayuki ORITANI Alfred HASSNER (Laboratory of Applied Bioorganic Chemistry, Division of Life Science, Graduate School of Agricultural Science, Tohoku University, 1-1 Tsutsumidori-Amamaiyamachi, Aoba-ku,Sendai 981 -8855, Japan)(Department of

出处《Chinese Chemical Letters》 SCIE CAS CSCD 1999年第8期629-632,共4页 中国化学快报（英文版）

关键词 DIASTEREOSELECTIVITY michael addition ALCOHOLS catalysts Diastereoselectivity, michael addition, alcohols, catalysts

分类号 O621 [理学—有机化学]

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Chinese Chemical Letters

1999年第8期

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High Diastereoselectivity in the Conjugate Addition of Functionalized Alcohols to a Chiral(E)-Nitroalkene

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