Determination of Sparfloxacin in Human Urine by Reversed-Phase High Performance Liquid Chromatography With Nitrous Acid and Hydroiodic Pre-Column Derivatization 被引量：1

Determination of Sparfloxacin in Human Urine by Reversed-Phase High Performance Liquid Chromatography With Nitrous Acid and Hydroiodic Pre-Column Derivatization

下载PDF

导出

摘要 Sparfloxacin can be oxidized by nitrous acid, then react with hydroiodic acid to form a fluorescent derivative. Based on this, a reversed-phase high performance liquid chromatographic pre-column derivatization new method is described for the determination of sparfloxacin in human urine. The linear range is 0.05 mg/L to 4.0 mg/L, the recoveries are 91.5%similar to 95.7% and the RSD is 1.2%similar to4.2%. The results showed that this method is suitable for the determination of sparfloxacin in human urine. Sparfloxacin can be oxidized by nitrous acid, then react with hydroiodic acid to form a fluorescent derivative. Based on this, a reversed-phase high performance liquid chromatographic pre-column derivatization new method is described for the determination of sparfloxacin in human urine. The linear range is 0.05 mg/L to 4.0 mg/L, the recoveries are 91.5%similar to 95.7% and the RSD is 1.2%similar to4.2%. The results showed that this method is suitable for the determination of sparfloxacin in human urine.

作者 Li Ming DU Zhe Feng FAN Jin Li QIAO Jing Ping WANG

机构地区 Analysis and Test Center Department of Chemistry

出处《Chinese Chemical Letters》 SCIE CAS CSCD 2001年第11期1007-1010,共4页 中国化学快报（英文版）

关键词 SPARFLOXACIN HPLC pre-column derivatization human urine sparfloxacin HPLC pre-column derivatization human urine

分类号 O657.7 [理学—分析化学]

引文网络
相关文献

同被引文献11

1Rui Nian HUA,Zhi Hong JIA,De Min XIE,Chun Shan SHI.Synthesis of the Complex Fluoride LiBaF_(3) through a Solvothermal Process[J].Chinese Chemical Letters,2002,13(10):1021-1024. 被引量：2
2Wang X,Zhang J,Peng Q,Li Y D.Hydrothermal synthesis of rare-earth fluoride nanocrystals[].Inorganic Chemistry.2006 被引量：1
3Wankiyn B M.Flux growth of crystals og some transition metal fluorides Part1,[].Journal of Materials.1975 被引量：1
4Zhao C,Feng S. H,Xu R. et al.under Mild Conditions[].Chemical Communications.1997 被引量：1
5He L J,Yuan H M,Huang K K,et al.Hydrother-mal synthesis,structure,and magnetic properties of (NH4)2NaVF6 and Na3VF6[].Journal of Solid State Chemistry.2009 被引量：1
6Alter Von E,Hoppe R.Cs2MVF6 und Rb2MVF6 (M=Tl, K und Na): mit einer Bemerkungüber Na3VF6.[].anorg Allg Chem.1975 被引量：1
7McLain E S,Dolgos R M,Tennant A D,et al.Mag-netic behaviour of layered Ag (II)fluorides[].NatMater.2006 被引量：1
8Mimi L M,Pennec Y,Bassat J M,et al.Magneticproperties of the iron chromium fluoride mixed series[].Journal of Magnetism and Magnetic Materials.1994 被引量：1
9Strempter J,Rütt U,Bayrakci P S.Magnetic proper-ties of transition metal fluorides MF2 (M=Mn,Fe,Co,Ni)via high-energy photon diffraction[].Physical Review B Condensed Matter and Materials Physics.2004 被引量：1
10Chicklis E P,Naiman C S,Folweiler R C,et al.High-efficiency room-temperature 2.06μm laser usingsensitized Ho3+:YLF[].Applied Physics Letters.1971 被引量：1

引证文献1

1赫丽杰,张冬,冯守华,陈岗,邹勃.冰晶石型氟化物K_3VF_6的水热合成表征及磁学性质研究[J].材料开发与应用,2012,27(4):55-58. 被引量：1

二级引证文献1

1赫丽杰,张冬,谭广雷,牟涛,刘海燕,杜鹏.冰晶石型氟化物(NH_4)_3FeF_6的水热合成及其磁学性质[J].合成化学,2017,25(4):326-329.

1JinMao YOU,Bin ZRAO,QingCun ZHU(Department of Chemistry, Qufu Normal University, Qufu. Shandong 273 165).High－Performance　Liquid　Chromatographic　Determination　Of　N－Nitrosoamines　by　Pre－Column　Fluorescence　Derivatization　with　9－Phenanthrene　Chloride[J].Chinese Chemical Letters,1996,7(12):1113-1116.
2Du, LM,Zhou, J,Xu, QQ,Fan, ZF,Yuan, R.Study on Fluorescence Property of Sparfloxacin Derivatizing System and its Application[J].Chinese Chemical Letters,2000,11(3):255-258. 被引量：1
3Yang QIN,Chang Jiu ZHANG,You Xuan XU,Shao Tang ZHU (National Research Institute of Sports Medicine,Beijing 100029).GC/MS CONFIRMATORY METHOD OF BENZTHIAZIDE IN HUMAN URINE[J].Chinese Chemical Letters,1995,6(6):497-500.
4Jin Mao YOU,Xing Jun FAN,Qing Yu OU,Qing Cun ZHU(Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences 730000)(Department of Chemistry, Qufu Normal University, Qufu, Shandong 273165).HPLC Determination of Amino Acids by Pre-Column Fluorescence Derivatization with Carbazole-9-yl-Acetyl Chloride[J].Chinese Chemical Letters,1998,9(3):281-285.
5Jin Mao YOU,Xin Jun FAN,Qing Yu OU,Qing Cun ZHU (Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences 730000)(Department of Chemistry, Qufu Normal University, Qufu, Shandong 273165).Liquid Chromatography Detertmination of Amino Acids by Pre-Column Fluorescence Derivatization with Acridone-N-acetyl Chloride[J].Chinese Chemical Letters,1998,9(7):657-660.
6LIU Yancheng,LI Haixia,CUI Rongrong,TANG Ruizhi,XU Yulie,WANG Wenfeng.Pulse radiolysis of sparfloxacin in neutral aqueous solution[J].Nuclear Science and Techniques,2013,24(B12):63-66. 被引量：2
7GUOMing,ZOUJian-wei,YIPing-gui,SHANGZhi-cai,HUGui-xiang,YUQing-sen.Studies on Reaction Mechanism Between Sparfloxacin and Bovine Serum Albumin[J].Chemical Research in Chinese Universities,2004,20(1):81-87.
8LI Gao-liang,HE Hui.Reaction Kinetics Between Nitrous Acid and N,N-dimethylhydroxylamine[J].Annual Report of China Institute of Atomic Energy,2009(1):282-283.
9张英,黄琳娟,王仲孚.A Sensitive Derivatization Method for the Determination of the Sugar Composition after Pre-column Reductive Amination with 3-Amino-9-ethylcarbazole （AEC） by High-Performance Liquid Chromatography[J].Chinese Journal of Chemistry,2007,25(10):1522-1528. 被引量：1
10QIU Pei hong (Department of Chemistry, Wenzhou Medical College, Wenzhou, 325003) ZHANG Hua shan, XU Guo liang and CHENG Jie ke (Department of chemistry, Wuhan University, Wuhan, 430072).Determination　of　Amino　Acidsas　Their　N-Hydroxy-succinimidyl-3-indolylacetate　Derivatives　by　Reversed-phase　HPLC[J].Chemical Research in Chinese Universities,1997,13(1):16-22.

Chinese Chemical Letters

2001年第11期

浏览历史

内容加载中请稍等...

Determination of Sparfloxacin in Human Urine by Reversed-Phase High Performance Liquid Chromatography With Nitrous Acid and Hydroiodic Pre-Column Derivatization 被引量：1

同被引文献11

引证文献1

二级引证文献1

相关作者

相关机构

相关主题

浏览历史