摘要
合成了一种新的尾式卟啉５－邻［４－（３－吡啶氧基）丁氧基］苯基－１０，１５，２０－三苯基卟吩（简称ｏ－ＰｙＴＰＰ），并以ｏ－ＰｙＴＰＰ为配体合成了金属铁卟啉ｏ－ＰｙＴＰＰＦｅ（Ⅲ）Ｃｌ和金属锰卟啉ｏ－ＰｙＴＰＰＭｎ（Ⅲ）Ｃｌ。通过元素分析、质谱、紫外可见光谱、红外光谱、核磁共振氢谱、顺磁共振波谱等手段进行了表征，结果表明，三价金属卟啉处于高自旋状态。
A new tailed porphyrin which bears covalently attached pyridine as an axial ligand,5 o [4 (3 pyridyloxy)butoxy]phenyl 10,15,20 triphenylporphine ( o PyTPP) and its iron coordination compound ( o PyTPPFe(Ⅲ)Cl) as well as manganese coordination compound ( o PyTPPMn(Ⅲ)Cl) have been synthesized.These compounds were characterized by elemental analysis,MS,UV vis,IR, 1HNMR and EPR spectra.Studies show that the metal ions of metalloporphyrins are of high spin state.
出处
《化学试剂》
CAS
CSCD
1998年第1期11-12,19,共3页
Chemical Reagents
基金
国家自然科学基金
广东省自然科学基金
兰州大学应用有机化学国家重点实验室资助
