摘要
把偶氮化合物对硝基双甲胺基偶氮苯作为客体掺杂到主体PMMA中利用旋涂法制备成薄膜,然后对薄膜进行电晕极化和全光极化,利用二次谐波产生法研究薄膜的非线性光学特性.实验结果表明:电晕极化后在测量的10 min内薄膜的二次谐波信号几乎没发生驰豫,但全光极化后的薄膜其二次谐波信号衰减近一半.这主要是由于电晕极化和全光极化的作用机制不同所导致.
The host-guest adulterate films,that the host was PMMA and guest was 4'-Nitro-4- dimethylaminoazobenzene,were prepared. The nonlinear optical properties of the films were investigated by using second harmonie generation technology after corona poling and All-optical poling. The experimental results were shown that the second harmonic signal is almost no relaxation in 10 minutes after eorona poling, but it decreases nearly half for All-optical poling. This was mainly due to the different mechanism between corona poling and all-optical poling.
出处
《聊城大学学报(自然科学版)》
2008年第4期50-52,110,共4页
Journal of Liaocheng University:Natural Science Edition
基金
国家自然科学基金(10874063)
山东省自然科学基金(Y2007A34)
山东省教育厅科技发展计划(J07YI05)资助课题
关键词
主客体掺杂
薄膜
驰豫
电晕极化
全光极化
host-guest adulterant,thin films,relaxation,corona poling,all-optical poling