摘要
从链引发、链增长两个方面对控制/活性阳离子聚合及其最新研究进展进行了综述。介绍了茂金属类、水溶性Lewis类和烷基铝等几类新型的引发体系,以及亲核试剂、沉淀平衡和"阳离子池"在控制链增长方面的应用。
The progress of controlled/living cationic polymerization including several novel initiating systems such as metallocenes, water-soluble Lewis acids and alkylaluminiums were introduced. The applications of nucleophile, precipitation equilibrium and ＂cationic pool＂ technique in controlled chain propagation were summarized.
出处
《化学通报》
CAS
CSCD
北大核心
2009年第3期229-237,共9页
Chemistry
基金
国防科工委"十一五"计量重点项目(J142006A201)资助
关键词
控制/活性阳离子聚合
引发体系
链增长
活性中心
Controlled/living cationic polymerization, Initiating system, Chain propagation, Active center
