摘要
以水热法为基础,向其溶胶中掺入适量的P25(二氧化钛粉体),来制备纳晶TiO_2胶体,以纳晶TiO_2为电子传输体组装染料敏化太阳能电池.通过XRD、SEM、UV-vis和电池的光电性能测试,来分析掺入P25对染料敏化太阳能电池性能的影响.结果表明,加入适量P25([P25]/[Ti]=0.2)后,染料敏化太阳能电池性能达到最佳值,在100 mW/cm^2光照条件下,光电转换效率达到5.4%.
Nano-crystalline titanium dioxide （TiO2） colloid was prepared from mixing TiO2 nano- crystalline P25 to sol by hydrothermal method. Using the nano-crystaUine TiO2 as the electron transmission medium, a dye-sensitized solar cell （DSSC） was assembled. The influence of amount of mixing P25 on the photoelectronic properties of the DSSC yeas confirmed by XRD pattern, SEM observation, UV-vis spectra, and I-V curve of the solar cells. The results show that when mixing proper P25 （ [P25]/[Ti] = 0.2） to sol, the photoelectric performance of the DSSC is the best. The photoelectric conversion efficiency with the film electrode could be 5.4 % irradiated by a solar simulator with 100 mW/cm^2.
出处
《影像科学与光化学》
EI
CAS
CSCD
2008年第6期499-506,共8页
Imaging Science and Photochemistry
基金
国家自然科学基金资助项目(50572022
50372030)
教育部科学技术研究重点项目(206074)
福建省自然科学基金资助项目(E0640003
E0210023
E0110026)
关键词
水热法
纳晶TiO2
染料敏化太阳能电池
hydrothemaal method
nano-crystallne TiO2
dye-sensitized solar cell
