摘要
研究了由部分水解聚丙烯酰胺水溶液交联得到的用于三次采油的弱凝胶体系,使用不同交联剂的水凝胶体系表现出不同的流变特性,反映两种不同织态结构的弱凝胶,一种为接近于均匀分形交联网的整体凝胶,另一种为有特征尺度的非均匀交联网的胶态分散凝胶.上述结果得到了光学显微镜观测的证明.强剪切和拉伸流的结果表明,当凝胶体系中存在大量胶团时,强剪切可以加强体系中网络结构的完整性,使得流变性质加强,不同于一般凝胶的减弱趋势.
The weak gels based on partial hydrolyzed polyacrylamide （HPAM） aqueous solutions gelated by organic crosslinkers were investigated rheologically with application background of tertiary oil recovery. The linear and non-linear rheological properties in gelation processes of weak gels with different erosslinkers reveal two kinds of textures near the gel point, one is a fraetal network, and the other is a heterogeneous network with a characteristic dimension. The optical microscopic approved the rheological arguments. High shearing and the stretch flow in converging outlet measurements indicat that contrary to the static colloidal gels, the strong flows can reinforce the integrities of network structures and enhance the rheological properties. The potential in the EOR applications are also discussed.
出处
《高等学校化学学报》
SCIE
EI
CAS
CSCD
北大核心
2008年第9期1908-1913,共6页
Chemical Journal of Chinese Universities
基金
胜利油田“智才”项目基金(合同号:智才2007)
国家自然科学基金(批准号:20490220)
国家“九七三”计划(批准号:2003CB615604)资助
关键词
水解聚丙烯酰胺
弱凝胶
流变性
凝胶织构
拉伸黏度
Hyalrolyzed polyarylamide
Weak gel
Rheology
Gel texture
Elongational viscosity
