摘要
目的设计合成2种新型的对称草酰胺、席夫碱桥连配体。方法用草酸二乙酯和乙二胺合成N,N'-二(2-氨乙基)-乙二酰胺,然后再与邻香兰素、香兰素反应合成了两种最终化合物。结果合成了化合物:N,N'-双(3-甲氧基水杨醛叉缩胺乙基)草酰胺(H4Lc)和N,N'-双(4-甲氧基水杨醛叉缩胺乙基)草酰胺(H4Ld)。结论利用元素分析、红外光谱、核磁谱图、紫外光谱、熔点测定等表征手段,最终确定了两种化合物的组成结构。
Aim Two new symmetrical oxalamides, Schiff base bridging ligands were designed and synthesized. Methods The final two compounds were synthesized via a series of reaction： diethyl oxalate and ethylenediamine, and then N, N′-bis （2 - aminoethyl） - ethylene amide and o -vanillin, vanillin. Results N, N′-bis（3-methoxy salicyl aminal ethylene）oxalamide （H4Lc） and N, N′-bis（4- methoxy salicyl aminal ethylene）oxalamide （H4 Ld） were synthesized. Conclusion The composition of compounds H4Lc and H4Ld were identified by elemental analysis, IR spectrum, NMR, UV spectrum and melting point menstruation.
出处
《宝鸡文理学院学报（自然科学版）》
CAS
2008年第3期203-205,共3页
Journal of Baoji University of Arts and Sciences(Natural Science Edition)
关键词
草酰胺
桥联配体
合成
表征
oxalamide
bridging ligand
synthesis and character
