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温度对氢气还原热轧碳钢表面氧化皮的影响 被引量:9

Effect of temperature on hydrogen gas reduction of oxide scale on carbon steel
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摘要 热轧碳钢BRC3表面氧化皮由最外Fe2O3层、中间Fe3O4层及最内FeO层组成,Fe3O4层与FeO层的厚度比约1∶3。在氧化皮的加热过程中,加热温度低于500℃,氧化皮的成分及结构保持不变;加热温度升高至600℃,FeO层内有大量Fe3O4析出;加热温度为700℃,氧化皮中只存在单一的FeO层。在氢还原过程中,还原温度为400℃时,仅有表层很小一部分氧化皮被还原,当还原温度为500℃时,氧化皮完全被还原为金属铁;但当还原温度升高至600及700℃时,还原效果反而略有下降。 Oxide scale formed on BRC3 carbon steel consists of outer Fe2O3 layer, intermediate Fe3O4 layer and inner FeO layer. Ratio of thickness of Fe3O4 layer and FeO layer is about 1: 3. Before hydrogen reduction, when temperature is below 500℃, the composition and structure of oxide scale remain unchanged. When temperature is up to 600℃, a large amount of Fe3O4 precipitates within original FeO layer. When temperature is 700℃, all oxides is transformed into FeO completely. During hydrogen reduction, only a little amount of oxide scale is reduced when temperature is 400℃. While temperature reaches 500℃, oxide scale is completely reduced by hydrogen gas. But the effect of increasing temperature on hydrogen gas reduction becomes less when temperature rises from 600 to 700℃.
出处 《材料热处理学报》 EI CAS CSCD 北大核心 2008年第4期166-169,共4页 Transactions of Materials and Heat Treatment
关键词 温度 氢气还原 热轧碳钢 氧化皮 temperature hydrogen gas reduction hot-rolled carbon steel oxide scale
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