摘要
无机纳米-高分子杂化材料具有优异的性能及广阔的应用前景,引起人们的广泛关注。本文综述了无机纳米材料表面引发自由基可控聚合反应在合成无机-高分子纳米杂化材料方面的广泛应用,包括表面引发原子转移自由基聚合(ATRP)、表面引发可逆加成-断裂链转移自由基聚合(RAFT)、表面引发稳定氮氧自由基聚合(NMP)。着重总结了近几年来这类杂化材料在功能性研究上新的进展,并对今后研究的发展趋势进行了展望。
The inorganic-polymer hybrid nanomaterials have many excellent properties. They are becoming increasingly important for various applications ranging from biomaterials to semiconductors in many fields and arouse much interest of scientists all over the world. This review highlights the development of surface-initiated living radical polymerizations from the inorganic materials including surface-initiated atom transfer radical polymerization （ATRP）, surface-initiated addition-fragmentation chain transfer radical polymerization （RAFY）, surface-initiated nitroxide- mediated polymerization （NMP） in the preparation of inorganic-polymer hybrid nanomaterials. The emphasis is put upon the new developments of various approaches taken to prepare hybrid nanomaterials in the recent years. Also, new research trends are pointed out.
出处
《化学进展》
SCIE
CAS
CSCD
北大核心
2008年第7期1122-1127,共6页
Progress in Chemistry
基金
国家自然科学基金项目(No.50373023
20574042
50433020)资助
关键词
无机纳米材料
表面引发聚合
引发体系
inorganic nanomaterials
surface initiated polymerization
initiation systems
