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咪唑类离子液体的研究进展 被引量:27

Imidazolium-Based Ionic Liquids
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摘要 咪唑类离子液体以其独特的物理化学性质和在众多领域的巨大应用潜能而引起广泛的关注。本文结合我们的研究工作,对近期国际上关于咪唑类离子液体的气-液和液-液平衡、咪唑类离子液体的表面活性剂行为、传统表面活性剂在咪唑类离子液体中聚集体的形成、表面活性剂/水(油)/咪唑类离子液体三元体系超分子自组装体形成等方面的一些主要研究成果进行了综合评述。在此基础上,提出了进一步开展非传统表面活性剂/离子液体体系超分子自组装体及离子液体结构对聚集体形成、结构、性质影响等研究的设想。 The unique physicochemical properties of imidazolium-based ionic liquids (IBILs) have attracted increasing interests due to their potential applications in various areas. In this paper, combining with our works, recent progress in some physicochemical properties of IBILs have been reviewed and discussed, including the gas-liquid and liquid-liquid equilibrium of IBILs, the surfactant behaviour of IBILs, the aggregations of traditional surfactant in IBILs, as well as the supramolecular self-assemblies formed in surfactant/IBILs/water(or oil) ternary systems. Suggestions for further studies have been proposed to investigate the self-assemblies formed in non-traditional surfactant/IBILs systems and to make clear that how the structures of IBILs influence the formation and properties of surfactant self-assemblies.
出处 《化学进展》 SCIE CAS CSCD 北大核心 2008年第7期1057-1063,共7页 Progress in Chemistry
基金 山东省自然科学基金项目(Y2006B29)资助
关键词 咪唑类离子液体 溶解平衡 超分子自组装体 imidazolium-based ionic liquids (IBILs) solubility equilibrium supramolecular self-assemblies
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