摘要
在对芳香磺酸存在下,以钨酸钠为催化剂,在回流温度(T=91～92℃)用30%H2O2氧化环己烯合成己二酸,获得了较高的收率,分离产率可达54.0%～75.1%.该方法不使用有机溶剂和相转移剂,操作简便、对环境无污染.
Synthesis of adipic acid by cyclohexene oxidatiori with aqueous 30% hydrogen peroxide has been carried out in excellent yield in the presence of sodium tungstate and aromatic sulfonic acid, yields of insolated are 54.0 %-75.1%. This no-solvent and entirely halide-free method is a simple, cost-effective and environmentally friendly process.
出处
《石家庄学院学报》
2008年第3期11-13,共3页
Journal of Shijiazhuang University
关键词
环己烯
过氧化氢
芳香磺酸
己二酸
环境友好合成
cyclohexene
hydrogen peroxide
aromatic sulfonic acid
adipic acid
environmentally benign synthesis
