摘要
A kind of pseudo-hypercrosslinked polymer resin was firstly synthesized via a continuous Friedel-Crafts alkylation poly- merization of benzene, diphenyl and their dichloromethyl derivatives. And the micromorphology and adsorption properties of these resins were investigated. The results demonstrated that the novel resins have high-specific surface area (581.26-974.88 m^2/g), high- pore volume (0.56-1.65 mL/g), small average porous radius (1.93-3.67 nm) and excellent adsorption properties for small non-polar organic molecules.
A kind of pseudo-hypercrosslinked polymer resin was firstly synthesized via a continuous Friedel-Crafts alkylation poly- merization of benzene, diphenyl and their dichloromethyl derivatives. And the micromorphology and adsorption properties of these resins were investigated. The results demonstrated that the novel resins have high-specific surface area (581.26-974.88 m^2/g), high- pore volume (0.56-1.65 mL/g), small average porous radius (1.93-3.67 nm) and excellent adsorption properties for small non-polar organic molecules.
基金
the financial support of the National Natural Science Foundation of China (No. 20574063).