摘要
Based on the construction of TTT diagrams by isothermal DSC measurements, the thermal stabilities of Zr65Cu27.5Al7.5 glassy alloys containing 0.68% and 0.06% [O] (molar fraction) were compared. The changing tendencies of the thermal stabilities reflected in the TTT-diagrams were validated by XRD analyses and TEM observations. The crystallization kinetic characteristics of oxygen-induced I-phase and Zr2Cu phase in Zr65Cu27.5Al7.5 glassy alloy were discussed. It is found that oxygen promotes the precipitation of I-phase and retards the formation of Zr2Cu phase. If the pre-crystallization event for oxygen-induced I-phase is permitted and the main-crystallization event for Zr2Cu phase is taken as the thermal stability criterion, the alloy with higher oxygen content has longer onset time for crystallization within a rather large supercooling temperature range. The possibility for the preparation of Zr65Cu27.5Al7.5 glassy alloy-based composite containing oxygen-induced I-phase was also forecasted.
Based on the construction of TTT diagrams by isothermal DSC measurements, the thermal stabilities of Zr65Cu27.5A17.5 glassy alloys containing 0.68% and 0.06% [O] （molar fraction） were compared. The changing tendencies of the thermal stabilities reflected in the TTT-diagrams were validated by XRD analyses and TEM observations. The crystallization kinetic characteristics of oxygen-induced I-phase and Zr2Cu phase in Zr65Cu27.sm17.5 glassy alloy were discussed. It is found that oxygen promotes the precipitation of I-phase and retards the formation of Zr2Cu phase. If the pre-crystallization event for oxygen-induced I-phase is permitted and the main-crystallization event for Zr2Cu phase is taken as the thermal stability criterion, the alloy with higher oxygen content has longer onset time for crystallization within a rather large supercooling temperature range. The possibility for the preparation of Zr65Cu27.sm17.5 glassy alloy-based composite containing oxygen-induced I-phase was also forecasted.
出处
《中国有色金属学会会刊：英文版》
CSCD
2008年第3期610-616,共7页
Transactions of Nonferrous Metals Society of China
基金
Project(50671076) supported by the National Natural Science Foundation of China
关键词
金属性玻璃
热力学研究
相位转换
杂质氧化
metallic glasses
thermodynamic properties
phase transition
oxygen impurity
