摘要
利用原位红外跟踪技术和光-示差扫描量热技术研究了不同类型多官能巯基化合物与乙烯基硅氮烷的紫外光聚合动力学过程.结果表明,巯基化合物官能度越高,聚合反应速率越高,但最终转化率越低.巯基丙酸酯类化合物比烷基硫醇类化合物更易与乙烯基硅氮烷反应.在较低温度下,反应温度对聚合反应的影响较弱,反应活化能约为2.3kJ/mol,而较高反应温度下反应速率偏离Arrhenius方程.
The UV curing kinetics of thiol-vinyl silizane were investigated by in-situ FT-IR and differential photo-scanning calorimetry. Results indicated that, the polymerization rate at peak maximum is promoted and the final unsaturation conversion is decreased with increasing the functional degrees of thiol group, the polymerization rate of alkyl 3-mercaptopropionate-vinyl silizane is greater than that of alkyl thiol-vinyl silizane. The photo-polymerization characteristic is little sensitive to reacting temperature under lower temperature, the apparent activation energy is 2.3 kJ/mol, but in higher temperature the rate of photo-polymerization deviates from Arrhenius equation.
出处
《影像科学与光化学》
EI
CAS
CSCD
2008年第3期218-223,共6页
Imaging Science and Photochemistry
基金
国家自然科学基金(20574056)
装备预研基金(9140A12070106HK0338)
西北工业大学博士论文创新基金(CX200614)
