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Effect of addition of Zn and Al elements on glass-forming ability and thermal stability of Mg-Cu-Y bulk metallic glasses 被引量:1

Effect of addition of Zn and Al elements on glass-forming ability and thermal stability of Mg-Cu-Y bulk metallic glasses
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摘要 After substituting partial Cu and Mg with Zn or Al elements for Mg65Cu25Y10 alloy,respectively,the metallic glass plate samples with thickness of 2-3 mm were prepared by water-quenching,their respective glass-forming ability and thermal stability were studied by using differential thermal analysis(DTA) and X-ray diffraction(XRD). Using Kissinger equation,the activation energies of crystallization of these metallic glasses heated with a constant rate were calculated. The results show that Al element is greatly harmful to the glass-forming ability of Mg-Cu-Y alloys and cannot acquire bulk amorphous alloys;nevertheless,the effect of Zn element addition is indeterminate for various components. The magnitudes of thermal stability are also revealed. After substituting partial Cu and Mg with Zn or Al elements for Mg65Cu25Y10 alloy, respectively, the metallic glass plate samples with thickness of 2-3 mm were prepared by water-quenching, their respective glass-forming ability and thermal stability were studied by using differential thermal analysis (DTA) and X-ray diffraction (XRD). Using Kissinger equation, the activation energies of crystallization of these metallic glasses heated with a constant rate were calculated. The results show that Al element is greatly harmful to the glass-forming ability of Mg-Cu-Y alloys and cannot acquire bulk amorphous alloys; nevertheless, the effect of Zn element addition is indeterminate for various components. The magnitudes of thermal stability are also revealed.
出处 《中国有色金属学会会刊:英文版》 CSCD 2007年第A02期1094-1098,共5页 Transactions of Nonferrous Metals Society of China
关键词 镁铜钇合金 金属玻璃 玻璃形成能力 热稳定性 Mg-based alloy metallic glasses glass-forming ability thermal stability
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参考文献11

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