摘要
为了探讨有机氯农药对牡蛎食用安全性的影响,对2003年春季在广东沿岸15个贝类养殖海域采集的近江牡蛎(Crassostrea rivularis)样品,用气相色谱仪-石英毛细管色谱柱(长30m,内径0.32mm,膜厚0.25μm)-微电子捕获检测器,测定持久性有机氯农药的残留量,然后进行健康风险评估。结果显示:α-BHC、β-BHC、γ-BHC、pp′-DDD、pp′-DDE、pp′-DDT、艾氏剂、狄氏剂、异狄氏剂、硫丹、七氯和环氧七氯的残留量均低于澳大利亚、美国、日本的食品安全限量;接触风险指数ERI和致癌风险指数CRI分别为4×10-7~4×10-2、1.17×10-5~8.97×10-5;每天每千克人体可以食用的广东近江牡蛎软组织重量,按可接受的致癌风险(CRI≤10-4)推算为4~51g,15个采样点总体平均为9g;按可接受的接触风险(ERI≤1)推算为37~410g,总体平均为68g。
In order to study the effect of organochlorine pesticides associated with consumption of oyster, samples of Jinjiang oyster ( Crassostrea rivularis ) were collected at 15 sites along the coast of Guangdong, China, during spring in 2003, certain chlorinated pesticides in the oyster body were determined by a gas chromatography equipped with an electron capture detector and a quartz capillary columns (30 m length×0.32 mm i.d. and 0.25 μm film thickness), risk of chlorinated pesticides to human health was evaluated. The detection results showed that the residue of α-BHC, β-BHC, γ-BHC, pp′-DDD, pp′-DDE, pp′-DDT, aldrin, dieldrin, endrin, endosulfan, heptachlor and heptachlor-epoxide was less than the sanitation criterion published by Australia, Japan and USA. The exposure risk index (ERI) was 4×10^-7~4×10^-2, and the carcinogenic risk index (CRI) was 1.17×10^-5~8.97×10^-5. It was suggested that the safe consumption of soft tissue of the oyster by one kilogram body weight of a person every day was 37~410 g with average of 68 g according to acceptable exposure risk (ERI ≤ 1), or 4~51 g with average of 9 g according to acceptable carcinogenic risk indexes(CRI ≤ 10^-4).
出处
《农业环境科学学报》
CAS
CSCD
北大核心
2007年第6期2323-2328,共6页
Journal of Agro-Environment Science
基金
社会公益研究专项资金项目(2005DIB3J021)
中国水产科学研究院基金项目(2003-5-4)
广东省科技计划项目(2003B21501)
关键词
有机氯农药
牡蛎消费
致癌风险
接触风险
chlorinated pesticides
oyster consumption
Carcinogenic risk
exposure risk