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聚乳酸立构选择性聚合的研究进展 被引量:3

Progress in stereoselective polymerization of poly (lactic acid)
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摘要 以高光学活性的聚乳酸合成为出发点,对近年来聚乳酸的非立构选择性聚合与立构选择性聚合的国内外研究进展进行了较详细的总结和评述;对聚乳酸立构选择性聚合的发展进行了预测,指出高效立构选择性催化体系的筛选和聚合工艺的优化是聚乳酸工业发展的关键。 From the view of the synthesis of poly (lactic acid) with high optical activity, the progress in the recent synthesis of poly(lactic acid) through stereoselective and non-stereoselective polymerization at home and aboard is summarized and reviewed.The prospect of stereoselective polymerization of poly(lactic acid) is also forecasted, the key to promote the development of poly (lactic acid) industry should be the selection of catalytic system with high stereoselectivity and the optimization of polymerization processes.
出处 《现代化工》 EI CAS CSCD 北大核心 2007年第10期20-24,共5页 Modern Chemical Industry
基金 国家自然科学基金资助项目(50573032) 南京林业大学人才基金资助项目(G2002-24)
关键词 聚乳酸 乳酸 丙交酯 立构选择性聚合 缩聚反应 poly(lactic acid) lactic acid lactide stereoselective polymerization polycondensation
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  • 1Proikakis C S, Tarantili P A, Andreopotdos A G. The role of polymer/ drug interactions on the sustained release from poly( D, L-lactic acid) tablets[ J]. Eur Polym J, 2006,42(12) : 3269 - 3276. 被引量:1
  • 2Huda M S, Drzal L T, Misra M, et al. Wood-fiber-reinforced poly(lactic acid) composites: Evaluation of the physico-mechanical and morphological properties [ J ]. J Appl Polym Sci, 2006,102 ( 5 ) : 4856 - 4869. 被引量:1
  • 3Furuhashi Y, Kimura Y, Yoshie N. Self-assembly of stereocomplex-type poly (lactic acid) [J]. Polym J,2006,38(10) : 1061 - 1067. 被引量:1
  • 4Amgotme A, Thomas Christophe M, Roisnel T, et al. Ring-opening polymerization of lactide with group 3 metal complexes supported by dianlOrllC ligands: Combining high activity, productivity, and selectivity [ J]. Chemistry: A European J, 2006, 12 ( 1 ) : 169 - 179. 被引量:1
  • 5Kricheldorf H R, Kreiser-Saunders I. Polylactones19 anionic polymerization of L-lactide in solutlon[J]. Makromol Chem, 1990, 191:1057 - 1066. 被引量:1
  • 6Kricheldorf H R, Dunsing R, Polylactones: 8. Mechanism of the cationic polymerization of L, L-dilactlde [J]. Makromol Chem, 1986, 187: 1611 - 1625. 被引量:1
  • 7Jacobs C, Dubois Ph, Jerome R, et al. Macromolecular engineering of polylactones and polylactides: 5. Synthesis and characterization of diblock copolymers based on poly-ε-caprolactone and poly( L, L or D, L- lactide) by aluminiumalkoxides[ J ]. Macromolecules, 1991,24: 3027 - 3034. 被引量:1
  • 8Schwach G, Coudane J, Vert M, et al. More about the polymerization of lactides in the presences of stannous octoate[ J ]. J Polym Sci A: Polym Chem, 1997,35:3431 - 3440. 被引量:1
  • 9Chen Hsuan-Ying, Huang Bor-Hunn, Lin Chu-Chieh. A highly efficient initiator for the ring-opening polymerization of lactides and caprolactone: A kinetic study [ J ]. Macromolecules, 2005,38 (13) : 5400 - 5405. 被引量:1
  • 10Ajioka M, Suizu K, Higuchi C, et al. Aliphatic polyesters and their copolymers synthesized through direct condensation polymerization[ J ]. Polym Degrad Stab, 1998,42:137 - 143. 被引量:1

二级参考文献30

共引文献133

同被引文献39

  • 1高勤卫,李明子,董晓.乙基纤维素共混改性聚乳酸的研究[J].南京林业大学学报(自然科学版),2006,30(1):37-40. 被引量:11
  • 2Platel R H, Hodgson L M, Williams C K. Bioeompatible initiators for laetide polymerization[J].Polym Rev, 2008, 48(1): 11-63. 被引量:1
  • 3Tang Z H, Yang Y K, Pang X, et al. Controlled and stereospecific polymerization of rac-lactide with a single-site ethyl aluminum and alcohol initiating system[J]. J Appl Polym Sci, 2005, 98(1): 102-108. 被引量:1
  • 4Gao Q W, Lan P, Shao H, et al. Direct synthesis with melt polyeondensation and microstructure analysis of poly (L-lactic acid-co-glycolic acid)[J].Polym J, 2002, 35(11):786-790. 被引量:1
  • 5Spassky N, Wisniewski M, Pluta C, et al. Highly stereoelecrive polymerization of rac-(D,L)- lactide with a chiral schiff's base/aluminium alkoxide initiator[J]. Macromol Chem Phys, 1996, 197:2627-2637. 被引量:1
  • 6Akihiro Ando, Kunio Kimura, Yuko Onda, et al. New attempt at the stereoseleetive polymerization of lactide by using crystallization during polymerizaion [J]. Macromolecular Rapid Communications, 2005, 26: 98-102. 被引量:1
  • 7Choi E J, Park J K, Chang H N. Effect of polymerization catalysts on the microstructure of poly(L-LA- co-εCL)[J].J Polym Sci Part B:Polym Phys, 1994, 32: 2481-2489. 被引量:1
  • 8Esoartero J L, Manolova S M, Manolova N, et al. NMR analysis of low molecular weight poly(lactic acid)s[J]. Macromoleculars, 1996,29:3535-3539. 被引量:1
  • 9Svhindler A, Harper D J. Poly(lactic acid) Ⅰ stereosequence distribution in the polymerization of racemic dilactide [J]. Polym Sci: Polym Lett, 1976, 14: 729-734. 被引量:1
  • 10Chamberlain B M, Cheng M, Moore D R, et al. Polymerization of lactide with zinc and magnesium beta- diiminate complexes: stereoeontrol and mechanism[J]. J Am Chem Soc, 2001, 123 (14):3229-38. 被引量:1

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