摘要
用过氧化物法合成了[Co(meamp)(amp)Cl][ZnCl4](meamp=2-[(N-甲基乙基)氨甲基]吡啶,amp=2-(氨甲基)吡啶)体系配合物的一异构体.元素分析及13C NMR,1H NMR检测表明,配合物是标题体系中的一异构体且配合物阳离子中可能具有C—H…π结构或C—H…π相互作用.
One isomer in [ Co( me, amp)(amp) Cl] [ ZnCl4 ] system was synthesized by decomposing per-oxide complexe ( meamp = 2- [ (N-methylethyl) aminomethyl ] pyridine, amp = 2- (aminomethyl) pyridine ). The isomer of the tetrachloride zincate salts of the comnplexes has been suggested to be the isomer with C-H…π structure or C-H…π interaction in title system by using element analysis and ^13 C NMR, ^1 H NMR spectra.
出处
《复旦学报(自然科学版)》
CAS
CSCD
北大核心
2007年第3期335-343,共9页
Journal of Fudan University:Natural Science
基金
贵州省自然科学基金资助项目(003060)
贵州省省长基金资助项目(20013004)