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Aerobic Oxidation of Benzyl Alcohol Catalyzed by Cu-Mn Mixed Oxides and 2,2,6,6-Tetramethyl-piperidyl-1-oxyl 被引量:6

Aerobic Oxidation of Benzyl Alcohol Catalyzed by Cu-Mn Mixed Oxides and 2,2,6,6-Tetramethyl-piperidyl-1-oxyl
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摘要 Heterogeneous Cu-Mn mixed oxides can mediate TEMPO-catalyzed selective oxidation of benzyl alcohol by molecular oxygen under neutral condition, and is recyclable. In the case of the molar ratio of Cu and Mn over 1, the highly-dispersed CuO inside the Cu-Mn mixed oxides is responsible for the good performances in catalytic oxidation. Heterogeneous Cu-Mn mixed oxides can mediate TEMPO-catalyzed selective oxidation of benzyl alcohol by molecular oxygen under neutral condition, and is recyclable. In the case of the molar ratio of Cu and Mn over 1, the highly-dispersed CuO inside the Cu-Mn mixed oxides is responsible for the good performances in catalytic oxidation.
出处 《Journal of Natural Gas Chemistry》 EI CAS CSCD 2007年第2期210-212,共3页 天然气化学杂志(英文版)
基金 the National Natural Science Foundation of China (No.20572102)
关键词 Cu-Mn oxides 2 2 6 6-tetramethyl-piperidyl-l-oxyl aerobic oxidation benzyl alcohol Cu-Mn oxides 2,2,6,6-tetramethyl-piperidyl-l-oxyl aerobic oxidation benzyl alcohol
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