摘要
A 3D supermolecular complex [Cu2I2(C8H6N2)]∞ has been synthesized in aqueous solution and structurally characterized by single crystal X-ray diffraction.[Cu2I2(C8H6N2)]∞ crystallizes in the monoclinic space group P21/n with a=4.7315(14) ,b=17.722(6) ,c=13.862(3) ,β=92.91(2) °,V=1160.8(6) 3,Z=4,ρ=2.924 g/cm3,F(000)=928,μ=8.943 mm-1,R=0.0482,wR2(I>2σ(I))=0.1038.According to X-ray crystallographic studies,each Cu(I) ion of [Cu2I2(C8H6N2)]∞ is tetra-coordinated with three iodine atoms and one nitrogen atoms from C8H6N2 to form a distorted tetrahedron.In this article we also measured the fluorescence property of the compound.
A 3D supermolecular complex [ Cu2I2 （C8H6N2 ）]∞ has been synthesized in aqueous solution and structurally characterized by single crystal X -ray diffraction. [ Cu2I2 （C8H6N2 ） ]∞ crystallizes in the monoclinic space group P21/nwith a = 4.7315（14） A°,b=17.722（6） A°,c=13.862（3） A°,β=92.91（2）° ,V=1160.8（6） A° Z=4, 0=2.924g/cm^3,F（000） = 928, μ = 8.943 mm^-1, R = 0.0482, wR^2 （ I 〉 2σ （I） ） = 0. 1038. According to X - ray crystallographic studies, each Cu （I） ion of [ Cu2I2 （C8H6N2 ）]∞ is tetra- coordinated with three iodine atoms and one nitrogen atoms from C8H6N2 to form a distorted tetrahedron. In this article we also measured the fluorescence property of the compound.
出处
《化学研究与应用》
CAS
CSCD
北大核心
2007年第6期675-678,共4页
Chemical Research and Application
关键词
碘化亚铜
喹喔啉
晶体结构
荧光
Copper （I） Iodide
Quinoxaline
Crystal Structure
Fluorescence
