摘要
苯乙烯和二乙烯苯共聚体系是典型的不可控制的交联聚合体系,加入天然橡胶后,通过阳离子聚合方法,生成三元共聚物线团,由于橡胶分子链上含有大量的双键,聚合体系中能进行分子内反应,使不可控的交联聚合体系成为可控的交联聚合体系,其链增长不能无限制进行,从而可以合成可溶解的交联的聚苯乙烯-二乙烯苯-天然橡胶聚合物。
Copolymerization of styrene and divinylbenzene is typical uncontrolled cross-linked system. When natural rubber was added into the system, ternary copolymer produced. Due to great amount of double bond on rubber chain, a lot of intramolecular reaction occurred in the system, which made the uncontrolled cross-linked system into a controlled cross-linked copolymerization, resulting in chain growth can＇t go illimitably in cross-linking process. Thus, soluble cross-linked poly （styrene-divinylbenzene-natural rubber） was synthesized.
出处
《高分子材料科学与工程》
EI
CAS
CSCD
北大核心
2007年第2期88-91,共4页
Polymer Materials Science & Engineering
关键词
分子内反应
分子间反应
可控的交联聚合
可溶解的交联大分子
intramolecular reaction
intermolecular reaction
controlled cross-linking polymerization
soluble cross-linked macromolecule
