摘要
通过电滞回线测试,探讨了xPb(Mn1/3Sb2/3)0.05(Zr1/2Ti1/2)0.95O3(1-x)Pb(Zn1/3Nb2/3)0.28(Zr1/2Ti1/2)0.72O3[xPMnS-(1-x)PZN]陶瓷的铁电性能及铁电相变特性。同时研究了Ba2+取代Pb2+对材料铁电性能的影响。结果表明:三方相含量较高的0.2PMnS-0.8PZN陶瓷具有较高的矫顽场和较大的剩余极化强度;四方相含量较高的0.5PMnS-0.5PZN和0.6PMnS-0.4PZN陶瓷具有较低的矫顽场和较小的剩余极化强度,Ba2+取代使三方相含量增加,铁电性能明显提高。
Through testing of the hysteresis loop, the ferroele.ctric properties and ferroelectric phase transition of xPb(Mn1/3Sb2/3)0.05(Zr1/2Ti1/2)0.95O3(1-x)Pb(Zn1/3Nb2/3)0.28(Z1/2Ti1/2)0.72O3 [xPMnS-(1-x)PZN] ceramics were cletermined. The effect of the substitution of Ba^2+ for Pb^2+ on .the ferroelectric properties of the material was also studied, The results show that 0.2PMnS-0.8PZN ceramic with high rhombohedral phase content has a higher coercive field and a larger remnant polarization, while 0.5PMnS-0.5PZN and 0.6PMnS-0.4PZN ceramics with high tetragonal phase content have a low.er coercive field and a smaller remnant polarization. The substitution of Ba^2+ for pb^2+ can increase the co.ntent of the rhombohedral phase and thus improve the f crroelectric properties of the material.
出处
《硅酸盐学报》
EI
CAS
CSCD
北大核心
2007年第2期174-177,共4页
Journal of The Chinese Ceramic Society
基金
国家自然科学基金(50402014)资助项目~~
关键词
锰锑酸铅-锌铌酸铅-锆钛酸铅陶瓷
铁电性能
压电陶瓷
钡取代
leo, d manganese antimony-lead zinc niohate-lead zirconate titanate ceramics
ferroelectric property
piezoelectric ceramics
substitution of barium