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相反转乳液接枝法合成EPDM-g-SAN及其对SAN树脂的增韧作用 被引量:6

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摘要 采用相反转乳液接枝法合成EPDM接枝聚苯乙烯-丙烯腈(EPDM-g-SAN),研究乳化剂质量分数、油相/水相(O/W)质量比和EPDM/单体质量比对聚合反应的影响以及EPDM-g-SAN对SAN树脂的增韧作用。结果表明,乳化剂质量分数为0.06、O/W质量比为100/100、EPDM/单体质量比为60/40时,聚合反应的单体转化率、接枝率和接枝效率最大;EPDM-g-SAN对SAN树脂增韧效果显著,其增韧机理以空穴化为主,兼有银纹化和剪切屈服。
出处 《橡胶工业》 CAS 北大核心 2007年第3期150-153,共4页 China Rubber Industry
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